کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1308004 | 975161 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Nickel(II) complexes bearing a pincer ligand containing thioamide units: Comparison between SNS- and SCS-pincer ligands Nickel(II) complexes bearing a pincer ligand containing thioamide units: Comparison between SNS- and SCS-pincer ligands](/preview/png/1308004.png)
Nickel(II) complexes bearing a κ3SNS pincer ligand, 2,5-bis(benzylaminothiocarbonyl)pyrrolyl (L1) and a κ3SCS-pincer ligand, 2,6-bis(benzylaminothiocarbonyl)phenyl (L2), were synthesized, and their structures and electrochemical properties were elucidated. The crystal structures of [Ni(SNS)Br] (2) and [Ni(SCS)Br] (5) were determined by X-ray crystallography. The electrochemical and crystallographic data obtained from the complexes revealed that the κ3SCS ligand has a stronger electron-donating ability than the κ3SNS ligand.
Two types of pincer nickel(II) complexes bearing a κ3SNS pincer ligand and a κ3SCS-pincer ligand were synthesized, and their electrochemical properties were elucidated. Electrochemical data of the complexes revealed that the κ3SCS ligand had a stronger electron-donating ability than the κ3SNS ligand.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 11, 10 August 2010, Pages 2474–2480