کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308052 | 975162 | 2006 | 6 صفحه PDF | دانلود رایگان |
Two new octahedral cluster complexes – [Re6S8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (1) and [Re6Se8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (2), where 3,5-Me2PzH is 3,5-dimethylpyrazole, have been synthesized using reaction of rhenium chalcobromide complexes Cs4[Re6S8Br6] · 2H2O and Cs3[Re6Se8Br6] · H2O, respectively, with molten 3,5-dimethylpyrazole. Both compounds synthesized were characterized by X-ray single-crystal diffraction and chemical analysis, IR and luminescent spectra.
Two new octahedral cluster complexes – [Re6Q8(3,5-Me2PzH)6]Br2 · 2(3,5-Me2PzH) (Q = S, Se), where 3,5-Me2PzH is 3,5-dimethylpyrazole, have been synthesized and characterized by X-ray single-crystal diffraction and chemical analysis, IR and luminescent spectra.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 359, Issue 4, 1 March 2006, Pages 1129–1134