کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308360 | 1499147 | 2016 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, structure and catalytic activity of bis(phenoxyiminato)iron(III) complexes in coupling reaction of CO2 and epoxides Synthesis, structure and catalytic activity of bis(phenoxyiminato)iron(III) complexes in coupling reaction of CO2 and epoxides](/preview/png/1308360.png)
• New bis(phenoxyiminato)Fe(III)-chloro complexes was synthesized and characterized with a variety of techniques.
• Iron catalysis is environmental benign and an attractive alternative for other transition metals.
• Selective synthesis of cyclic carbonates from CO2 and epoxides with high TON value.
Here we described the synthesis and characterization of a series of new bis(phenoxyiminato)Fe(III)-chloro complexes using a variety of techniques, including: elemental analysis, IR-, MS(EI), UV–Vis-spectroscopy, and X-ray diffraction. A solid-state structure of bis(N-salicylidene-3-phenylpropylamine)iron(III)chloride reveals a distorted square-pyramid coordination with crystallographic C2-symmetry wherein chloride occupies the axial position. Isolated complexes were also evaluated as catalysts for a coupling reaction of CO2 and various epoxides, including propylene, 1-hexene, cyclohexene and styrene oxides to form corresponding cyclic carbonates. Accordingly, the ligand structure and the solvent used influenced the catalytic activity and marked enhancement in the activity was observed using DMF as a solvent. Under optimized reaction conditions (145 °C and 10 bar of CO2) bis(N-salicylidene-2-phenylethylamine)iron(III)chloride gave cyclopropylene carbonate with considerable high TON value (1029) within 3 h.
Synthesis and characterization of new bis(phenoxyiminato)iron(III) complexes and their catalytic activity along with Bu4PBr for selective cyclic carbonate synthesis from epoxides and carbon dioxide.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 442, 1 March 2016, Pages 81–85