کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308371 1499147 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, characterization and ethylene oligomerization behavior of new nickel(II) octofluoro-α-diimine complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, characterization and ethylene oligomerization behavior of new nickel(II) octofluoro-α-diimine complex
چکیده انگلیسی
Novel nickel (II) complex supported by fluorinated ligand was synthesized and fully characterized. According to the X-ray complex (L2Ni2Br3·2Н2О)+Br− has distorted octahedral environment of nickel atoms. Been activated with either Et3Al2Cl3 or Et2AlCl, complex showed good activities in ethylene oligomerization. The addition of PPh3 to the Ni(II)-based systems enhanced the catalytic activity and switched the selectivity from terminal to internal olefins.97
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 442, 1 March 2016, Pages 167-171
نویسندگان
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