کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308466 975174 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, structure and electron-mediator properties of the mono- and difunctionalized macrobicyclic iron(II) tris-dioximates with thiol terminated ribbed spacer substituents
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, structure and electron-mediator properties of the mono- and difunctionalized macrobicyclic iron(II) tris-dioximates with thiol terminated ribbed spacer substituents
چکیده انگلیسی
Nucleophilic substitution of the reactive chlorine atoms of mono- and dichlorine-containing clathrochelate precursors with HSCH2CH2SH and (HSCH2CH2)2S afforded the clathrochelates with a sole terminal HS-containing spacer substituent and with two longchain sulfide spacer fragments, respectively. Application of clathrochelate self-assembled monolayer on gold electrode as a redox mediator for the precise and sensitive amperometric determination of hydrogen peroxide is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 9, 1 July 2009, Pages 2982-2988
نویسندگان
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