کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308591 975176 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+
چکیده انگلیسی
9-Methyladenium, 9-MeAH+, binds to cis-(NH3)2PtII via its N7 position to give 1:1 and 1:2 complexes, both of which have been isolated. The 1:2 complex is special in that it crystallizes with additional two equivalents of HNO3 per Pt, which are located in rectangular channels. pKa values of the 9-MeAH+ ligands have been determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Brought to you by:College of Engineering Chengannur - 'Renewal due by 31 Dec 2017'
نویسندگان
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