کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308591 | 975176 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+ Synthesis and X-ray crystal structure analysis of 1:1 and 1:2 complexes of cisplatin with the model nucleobase 9-methyladenine in its protonated form and a unique HNO3 adduct of cis-[(NH3)2Pt(9-MeAH-N7)2]4+](/preview/png/1308591.png)
چکیده انگلیسی
9-Methyladenium, 9-MeAH+, binds to cis-(NH3)2PtII via its N7 position to give 1:1 and 1:2 complexes, both of which have been isolated. The 1:2 complex is special in that it crystallizes with additional two equivalents of HNO3 per Pt, which are located in rectangular channels. pKa values of the 9-MeAH+ ligands have been determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Brought to you by:College of Engineering Chengannur - 'Renewal due by 31 Dec 2017'
Journal: Inorganica Chimica Acta - Brought to you by:College of Engineering Chengannur - 'Renewal due by 31 Dec 2017'
نویسندگان
Egla Yareth Bivián-Castro, Michael Roitzsch, Deepali Gupta, Bernhard Lippert,