کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308712 975180 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solvothermal synthesis, crystal structure and luminescence of the first organic amine templated europium sulfate
چکیده انگلیسی

The first organic amine templated europium sulfate [C2N2H10]1.5[Eu(SO4)3(H2O)] · 2H2O (1), has been synthesized under solvothermal conditions by using a mixture of n-butanol and water as the solvent. The colorless block crystals were characterized by IR, TGA and ICP. Crystal structure analysis shows that the corrugated layered framework of compound 1 is constructed from EuO9 polyhedra and sulfate groups, while non-coordination water molecules and ethylenediamine molecules link the adjacent layers by hydrogen bonds. Compound 1 represents a strong luminescence upon the excitation.

The structure of europium sulfates [Eu(SO4)3(H2O)][C2N2H10]1.5 · 2H2O (1), shows that the corrugated layer framework of 1 constructed from EnO9 polyhedra and sulfate groups. Non-coordination water molecules and ethylenediamine molecules link adjacent layer by using hydrogen bonds. Compound 1 existed strong luminescence upon excitation.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 8, 1 June 2009, Pages 2565–2568
نویسندگان
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