کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1308967 1499154 2015 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, characterization, electrochemical and magnetic study of mixed ligand mono iron and O-methoxy bridged diiron complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, characterization, electrochemical and magnetic study of mixed ligand mono iron and O-methoxy bridged diiron complexes
چکیده انگلیسی
The complexes cis-[Fe(5,5′-dmbipy)2Cl2]Cl and cis-[Fe(5,5′-dmbipy)2Cl2]ClO4 (5,5′-dmbipy is 5,5′-dimethyl-2,2′-bipyridine) were synthesized as precursors of new diiron complexes. The diiron complex [Fe(5,5′-dmbipy)(NCS)2(μ-OCH3)]2 was obtained from the reaction of KSCN with cis-[Fe(5,5′-dmbipy)2Cl2]Cl and cis-[Fe(5,5′-dmbipy)2Cl2]ClO4. Complex [Fe(5,5′-dmbipy)(NCS)2(μ-OCH3)]2 was obtained from the addition of KSCN to FeCl2·4H2O and then 5,5′-dmbipy. A new binuclear iron(III) complex [Fe(4bt)(NCS)2(μ-OCH3)]2 (4bt is 4,4′-bithiazole) has also been synthesized from the reaction of [Fe(4bt)3](NO3)2 with KSCN in a mixture of methanol/acetonitrile solvent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 435, 24 August 2015, Pages 262-273
نویسندگان
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