کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308967 | 1499154 | 2015 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization, electrochemical and magnetic study of mixed ligand mono iron and O-methoxy bridged diiron complexes
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The complexes cis-[Fe(5,5â²-dmbipy)2Cl2]Cl and cis-[Fe(5,5â²-dmbipy)2Cl2]ClO4 (5,5â²-dmbipy is 5,5â²-dimethyl-2,2â²-bipyridine) were synthesized as precursors of new diiron complexes. The diiron complex [Fe(5,5â²-dmbipy)(NCS)2(μ-OCH3)]2 was obtained from the reaction of KSCN with cis-[Fe(5,5â²-dmbipy)2Cl2]Cl and cis-[Fe(5,5â²-dmbipy)2Cl2]ClO4. Complex [Fe(5,5â²-dmbipy)(NCS)2(μ-OCH3)]2 was obtained from the addition of KSCN to FeCl2·4H2O and then 5,5â²-dmbipy. A new binuclear iron(III) complex [Fe(4bt)(NCS)2(μ-OCH3)]2 (4bt is 4,4â²-bithiazole) has also been synthesized from the reaction of [Fe(4bt)3](NO3)2 with KSCN in a mixture of methanol/acetonitrile solvent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 435, 24 August 2015, Pages 262-273
Journal: Inorganica Chimica Acta - Volume 435, 24 August 2015, Pages 262-273
نویسندگان
Farsheed Shahbazi-Raz, Vahid Amani, Ehsan Bahojb Noruzi, Nasser Safari, Roman BoÄa, Ján TitiÅ¡, Behrouz Notash,