کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1308982 | 1499211 | 2008 | 13 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and spectral properties of Zr(IV) and Hf(IV) phthalocyanines with β-diketonates as axial ligands Synthesis and spectral properties of Zr(IV) and Hf(IV) phthalocyanines with β-diketonates as axial ligands](/preview/png/1308982.png)
The series of new zirconium(IV) and hafnium(IV) phthalocyanines with various β-dicarbonyl ligands were prepared via direct interaction between di(chloro)zirconium(IV) or hafnium(IV) phthalocyanines and free β-diketones and also with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one. The structure of the obtained bis(β-dicarbonilato) zirconium(IV) and hafnium(IV) phthalocyanines was studied by two dimension 1H NMR spectroscopy (COSY, NOESY, ROESY). Absorption and fluorescence spectroscopic studies have been investigated in various solvents. Analyzed compounds of concentration range below 10−5 mol/dm3 do not aggregate in the organic solvents. Fluorescence quantum yields (ΦF) and natural life times (τ) of zirconium phthalocyanine complexes have been calculated in toluene, DMSO and THF.
Zirconium(IV) and hafnium(IV) phthalocyanines with β-dicarbonyl ligands were prepared via direct interaction between di(chloro)zirconium(IV) or hafnium(IV) phthalocyanines and free β-diketones and also with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one. The structure of the obtained bis(β-dicarbonilato) zirconium(IV) and hafnium(IV) phthalocyanines was studied by two dimension 1H NMR spectroscopy (COSY, NOESY, ROESY).Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 361, Issues 9–10, 27 June 2008, Pages 2569–2581