کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1308987 | 1499211 | 2008 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Two new N-heterocyclic carbene silver(I) complexes with the π–π stacking interactions Two new N-heterocyclic carbene silver(I) complexes with the π–π stacking interactions](/preview/png/1308987.png)
The precursors bis[N-(alkyl)benzimidazoliumylmethyl]durene halide (1a: alkyl = C2H5, halide = Br−; 1b: alkyl = n-C4H9, halide = Cl−; durene = 1,2,4,5-tetramethylbenzene) and their two new NHC silver(I) complexes [Durene(CH2BimyEtAgBr)2] (2a) and [Durene(CH2BimynBuAgCl)2] (2b) (Bimy = benzimidazol-2-ylidene) have been prepared and characterized. In the crystal structures of 2a and 2b the aromatic π–π stacking interactions are observed.
The precursors bis[N-(alkyl)benzimidazoliumylmethyl]durene halide (1a: alkyl = C2H5, halide = Br−; 1b: alkyl = n-C4H9, halide = Cl−; durene = 1,2,4,5-tetramethylbenzene) and their two new NHC silver(I) complexes[Durene(CH2BimyEtAgBr)2] (2a) and [Durene(CH2BimynBuAgCl)2] (2b) (Bimy = benzimidazol-2-ylidene) have been prepared and characterized. In the crystal structures of 2a and 2b the aromatic π–π stacking interactions are observed.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 361, Issues 9–10, 27 June 2008, Pages 2616–2622