A coordination polymer formed by cis-[(PMePh2)2Pt(NO3)2] and 2,5-bis(4-pyridyl)-1,3,4-thiadiazole

The 1:1 adduct formed from cis-[(PMePh2)2Pt(NO3)2] and 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (bpytdz) in chloroform crystallizes out as a 1D coordination polymer built up of cis-(PMePh2)2Pt units connected by the bpytdz ligand, an unusual self-assembly for a complex formed from a (phosphine)2PtII entity and a N,N linker.

The 1:1 adduct formed from cis-[(PMePh2)2Pt(NO3)2] and 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (bpytdz) crystallizes out as a 1D coordination polymer built up of cis-(PMePh2)2Pt units connected by the bpytdz ligand, an unusual self-assembly for a complex formed from a (phosphine)2PtII entity and a N,N linker.Figure optionsDownload as PowerPoint slide