کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309188 | 975198 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The supersilylated tetrasulfane tBu3Si-S4-SitBu3: Synthesis, structure, and its reaction behavior towards [Fe(CO)5]
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The supersilylated tetrasulfane tBu3Si-S4-SitBu3: Synthesis, structure, and its reaction behavior towards [Fe(CO)5] The supersilylated tetrasulfane tBu3Si-S4-SitBu3: Synthesis, structure, and its reaction behavior towards [Fe(CO)5]](/preview/png/1309188.png)
چکیده انگلیسی
The tetrasulfane tBu3Si-S4-SitBu3 was formed in high yield when S2Cl2 was treated with two equivalents of Na(thf)2SSitBu3 in thf. X-ray quality crystals of the tetrasulfane tBu3Si-S4-SitBu3 (monoclinic space group P21/c) were grown from a benzene solution at ambient temperature. UV-induced degradation of [Fe(CO)5] in the presence of the tetrasulfane tBu3Si-S4-SitBu3 led to the formation of the carbonyliron complex [Fe4(μ4−S)2(CO)11].
The tetrasulfane tBu3Si-S4-SitBu3 was obtained when S2Cl2 was treated with two equivalents of [Na(thf)2SSitBu3]2.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 363, Issue 7, 20 April 2010, Pages 1421–1424
Journal: Inorganica Chimica Acta - Volume 363, Issue 7, 20 April 2010, Pages 1421–1424
نویسندگان
Theresa I. Kückmann, Inge Sänger, Michael Bolte, Matthias Wagner, Hans-Wolfram Lerner,