کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309432 | 975209 | 2014 | 5 صفحه PDF | دانلود رایگان |
• NHC-palladacycle/Cu cocatalyzed oxidation and Suzuki reactions.
• Synthesis of biarylaldehydes from phenylboronic acids containing hydroxymethyl.
• Three adducts of palladacycle 1–3 have been synthesized and characterized.
Three cyclopalladated 6-bromo-2-ferrocenylquinoline complexes with NHCs and PPh31–3 have been synthesized and characterized by elemental analysis, IR, NMR and single-crystal X-ray diffraction. Their application to Suzuki coupling of phenylboronic acid containing hydroxymethyl was also investigated. An efficient 3/Cu cocatalyzed oxidation/Suzuki coupling of aryl chlorides with phenylboronic acids containing hydroxymethyl in air has been developed.
Three cyclopalladated 6-bromo-2-ferrocenylquinoline complexes with NHCs and PPh31–3 have been synthesized and characterized. An efficient 3/Cu cocatalyzed oxidation/Suzuki coupling of aryl chlorides with phenylboronic acids containing hydroxymethyl in air has been developed.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 423, Part A, 1 November 2014, Pages 11–15