کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1309540 | 975213 | 2009 | 8 صفحه PDF | دانلود رایگان |
The synthesis of functionalized indazoles at the 6-position of the indazole ring is developed. Such precursors give access to tris(indazolyl)borate ligands derived from the scorpionate ligands of Trofimenko. These tripodal ligands are truly bifunctional since they can coordinate a metal via the nitrogen centers of the indazolyl rings and be anchored on surfaces on the opposite side through their 6-functionalizations. Three pendant ester or thioether groups were selected to anchor metallic complexes onto, respectively, an oxide or a metallic surface in view of near-field microscopy experiments. These building blocks have been subsequently used as stator in a family of single molecular rotary motors. The architecture of such compounds is centered around half-sandwich complexes of the family of pentaphenylcyclopentadienyl hydrotris(indazolyl)borate ruthenium (II).
The synthesis of indazoles functionalized at the 6-position with three pendant ester or thioether groups is described as precursors of tris(indazolyl)borate scorpionate ligands designed to anchor metallic complexes onto, respectively, an oxide or a metallic surface. These building blocks have been subsequently used as stator in a family of single molecular rotary motors.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 12, 15 September 2009, Pages 4276–4283