A series of thiolato-bridged di- and trinuclear complexes derived from [Tp∗Rh(SPh)2(MeCN)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate)

From the reactions of a Rh(III) complex [Tp∗Rh(SPh)2(MeCN)] with Rh(I), Pd(II), Pt(II), Re(I), and Mo(0) complexes, a series of thiolate-bridged di- and trinuclear complexes were prepared and fully characterized.