کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309570 | 975213 | 2009 | 9 صفحه PDF | دانلود رایگان |

New tris(4,4-dimethyl-2-oxazolinyl)phenylboratoiridium(I) scorpionate-type compounds [Ir(ToM)L2] (L2 = η4-C8H12 and (CO)2) and electrophiles form adducts that contain a bidentate IrToM-coordination and an N–electrophile interaction of the third oxazoline instead of the oxidative addition product. The adduct with lithium chloride gives a unique heterobimetallic Li–O-oxazoline-N–Ir bridging structure that has been identified through X-ray crystallography. Density functional theory calculations provide thermodynamic data, orbital symmetries, and orbital energies that explain the formation of the observed iridium(I) products.
Tris(4,4-dimethyl-2-oxazolinyl)phenylboratoiridium(I) compounds [Ir(ToM)L2] (L2 = η4-C8H12 and (CO)2) and electrophiles react to form adducts. The adduct with lithium chloride gives a unique heterobimetallic Li–O-oxazoline-N–Ir bridging structure. Density functional theory calculations provide thermodynamic data, orbital symmetries, and orbital energies that explain the formation of the observed iridium(I) products.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 12, 15 September 2009, Pages 4517–4525