کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309607 | 1499169 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, structural, Continuous Shape Measure and bond valence sum characterization of bismuth(III) complexes of substituted dithiocarbamates and their solvothermal decomposition
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, structural, Continuous Shape Measure and bond valence sum characterization of bismuth(III) complexes of substituted dithiocarbamates and their solvothermal decomposition Synthesis, structural, Continuous Shape Measure and bond valence sum characterization of bismuth(III) complexes of substituted dithiocarbamates and their solvothermal decomposition](/preview/png/1309607.png)
چکیده انگلیسی
Geometrical distortions from iOh in tris(dithiocarbamato)bismuth(III) have been quantified by Continuous Shape Measure (CShM) analysis. BiS6 chromophore in [Bi(chmdtc)3] (1) is a distorted octahedron. The coordination geometry in [Bi(chedtc)3] (2) and [Bi(dchdtc)3] (3) should be described as distorted pentagonal pyramid. The higher BVS values observed in the present set of compounds support the fact that the Bi-S bonds are more covalent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 419, 1 August 2014, Pages 82-88
Journal: Inorganica Chimica Acta - Volume 419, 1 August 2014, Pages 82-88
نویسندگان
Subburayan Sivasekar, Kuppukkannu Ramalingam, Corrado Rizzoli, Nagarajan Alexander,