کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309608 | 1499169 | 2014 | 7 صفحه PDF | دانلود رایگان |
• Synthesis and structure of a new dinuclear Mn(III) complex of a tetradentate ligand.
• The complex shows high selectivity in the oxidation of cyclohexene and cyclohexane.
• The highest reported selectivity to cyclohexanol for manganese catalysts.
A novel chloride bridged dinuclear manganese(III) complex was prepared and its structure established by X-ray diffraction analysis. The complex showed high selectivity in H2O2 promoted oxidation of cyclohexane and cyclic alkenes. Under optimized conditions, 72% of cyclohexane conversion with 85% of selectivity for alcohol was achieved after 5 h. To the best of our knowledge this activity and remarkable selectivity to cyclohexanol is the highest for a manganese catalyst.
Synthesis and structure of a novel dinuclear manganese(III) complex are reported. A remarkable selectivity to the cyclohexanol has been accomplished by the manganese catalyst in the oxidation of cyclohexane using aqueous H2O2 as the oxidant without any cocatalyst.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 419, 1 August 2014, Pages 89–95