کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1309609 | 1499169 | 2014 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Decomposition of pentachloridooxidorhenates(VI) – A still underinvestigated source of rhenium complexes at different oxidation states Decomposition of pentachloridooxidorhenates(VI) – A still underinvestigated source of rhenium complexes at different oxidation states](/preview/png/1309609.png)
• Products of the phosphonium pentachloridooxidorhenates(VI) decomposition were crystallized.
• Salts with [ReVOCl4X]− (X = solvent molecule) or [ReVOCl4ReVIIO4]2− anions are obtained.
• Structure aspects, TGA and IR studies are presented.
Studies on decomposition of pentachloridooxidorhenates(VI) are described. The products are rhenium(V) salts with anions [ReVOCl4X]− (X = solvent molecule) or [ReVOCl4ReVIIO4]2− or, under proper conditions, hexachloridorhenates(IV), as well as salts with [ReOCl5]2− or [ReOCl4]− anions. The products are listed and characterized by X-ray diffraction studies, or TGA/IR in the selected cases.
Structure and properties of the products of pentachloridooxidorhenates(VI) decomposition under air are presented.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 419, 1 August 2014, Pages 96–104