کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1309868 | 975223 | 2009 | 5 صفحه PDF | دانلود رایگان |

Two luminescent Cd(II) complexes [RBzPy][Cd(SCN)3] for R = Cl (1) and Br (2) have been synthesized and structurally characterized. The Cd atoms are all N3S3 hexa-coordinated with six bridging SCN− and form infinite [Cd(SCN)3]∞ polymeric chains. The layer arrangement of the anionic chains was obtained using the larger halogenated benzylpyridyl cations. The luminescent properties of 1 and 2 in the solid state were investigated.
Two complexes [RBzPy][Cd(SCN)3] for R = Cl (1) and Br (2) have been synthesized and structurally characterized. The Cd atoms form infinite [Cd(SCN)3]∞ polymeric chains. The luminescent measurements showed broad blue-fluorescent emissions band with a maximum at 490 nm for 1 and 484 nm for 2.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 7, 15 May 2009, Pages 2391–2395