کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1309935 975225 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Potassium(I)thallium(I) heterometallic 3D polymeric mixed-anions compound, succinate-nitrate [K2Tl(μ-C4H4O4)(μ-NO3)]n
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Potassium(I)thallium(I) heterometallic 3D polymeric mixed-anions compound, succinate-nitrate [K2Tl(μ-C4H4O4)(μ-NO3)]n
چکیده انگلیسی
A three-dimensional polymeric KITlI heterometallic compound with mixes succinate and nitrate ligands has been synthesized and characterized. The arrangement of O-atoms for TlI suggests a gap or hole in the coordination geometry around this atom. Two hydrogen atoms of succinate situated 3.26 Å above the proposed site on the lone pair of TlI is oriented in such a way that it might be thought to be forming weak Tl-Lp⋯H-C hydrogen bond or agostic interactions, thus attaining of environment TlO5H2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 10, 1 July 2006, Pages 3379-3383
نویسندگان
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