An investigation of the mixed-bridge dinuclear complex [Pt2(μ-S)(μ-NH2)(PPh3)4]+

A reinvestigation of the platinum(I) sulfide complex [Pt2(μ-S)(PPh3)4] leads to identification and subsequent development of syntheses of the novel mixed amido-sulfido complex [Pt2(μ-S)(μ-NH2)(PPh3)4]+; the X-ray structure of the tetraphenylborate salt is reported.