کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1310047 975230 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Magnetic susceptibility equation for dinuclear high-spin cobalt(II) complexes considering the exchange interaction between two axially distorted octahedral cobalt(II) ions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Magnetic susceptibility equation for dinuclear high-spin cobalt(II) complexes considering the exchange interaction between two axially distorted octahedral cobalt(II) ions
چکیده انگلیسی

A new magnetic susceptibility equation has been obtained for dinuclear high-spin cobalt(II) complexes considering the exchange interaction between two axially distorted octahedral cobalt(II) ions. A computational program has been developed, and the temperature dependencies of the magnetic susceptibility have been demonstrated. A characteristic χA versus T curve due to the zero-field splitting was shown when the distortion parameter v was positive.

A new magnetic susceptibility equation has been obtained for dinuclear high-spin cobalt(II) complexes considering an exchange interaction between two axially distorted octahedral cobalt(II) ions. Theoretical χA versus T curves. Parameters: λ = −173 cm−1, κ = 0.93, J = −10 cm−1, v = 2, 2.5, 2.6, 2.7, 2.8, 2.9 and 3.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 7, 25 April 2006, Pages 2097–2100
نویسندگان
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