کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310347 | 975243 | 2007 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: [TmIII(hfac)3(NITPhOPh)]∞: A new member of a lanthanide-based Single Chain Magnets family [TmIII(hfac)3(NITPhOPh)]∞: A new member of a lanthanide-based Single Chain Magnets family](/preview/png/1310347.png)
The polymeric coordination compound of formula [Tm(hfac)3(NITPhOPh)]∞ (where NITPhOPh is a nitronyl-nitroxide radical) has been synthesized and found to belong to the only reported family of isostructural Single Chain Magnets. Both static and dynamic magnetic measurements have been performed, and a dependence of the out-of-phase signal on the frequency is observed below 3 K. Scaling procedures indicate Ising magnetic anisotropy. Comparison of the extracted parameters with those of the previously reported isostructural compounds confirms a trend along the lanthanide series.
The polymeric coordination compound of formula [Tm(hfac)3(NITPhOPh)]∞ (where NITPhOPh is a nitronyl-nitroxide radical) is synthesized and found to belong to the only reported family of isostructural Single Chain Magnets. Comparison of the extracted parameters with those of the previously reported isostructural compounds confirms a trend along the lanthanide series.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 360, Issue 13, 1 October 2007, Pages 3807–3812