کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310350 | 975243 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Relaxation dynamics of a photoinduced di-cobalt-tetraoxolene valence tautomer Relaxation dynamics of a photoinduced di-cobalt-tetraoxolene valence tautomer](/preview/png/1310350.png)
The temperature dependence of the relaxation dynamics of a dinuclear cobalt-tetraoxolene complex undergoing photoinduced valence tautomerism is reported and discussed. Two different regimes were detected, one at low (5–20 K) and a second at higher temperatures (20–35 K). The activation energy for the low temperature regime suggests a tunnelling process assisted by lattice phonons. In the thermally activated region the activation energy is far from that expected for the total-symmetric Co–O breathing mode, thus suggesting an important role for other internal vibrational modes.
The relaxation kinetics of the photoinduced metastable state of a dinuclear Co-tetraoxolene complex are reported and discussed. The analysis of the temperature dependence reveals that at low temperature a phonon assisted tunnelling process dominates, while a thermally activated one is responsible for the relaxation at higher temperatures.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 360, Issue 13, 1 October 2007, Pages 3825–3828