کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310359 | 975243 | 2007 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Searching for switchable molecular conductors: Salts of [M(dcbdt)2] (M = Ni, Au) anions with [Fe(sal2-trien)]+ and [Fe(phen)3]2+ Searching for switchable molecular conductors: Salts of [M(dcbdt)2] (M = Ni, Au) anions with [Fe(sal2-trien)]+ and [Fe(phen)3]2+](/preview/png/1310359.png)
Salts of [FeIII(sal2-trien)]+and [FeII(phen)3]2+ cations and M[(dcbdt)2]− anions with M = Ni and Au (dcbdt = dicyanobenzenedithiolate) with formula [Fe(sal2-trien)] [M(dcbdt)2] and [Fe(phen)3] [M(dcbdt)2]2 were obtained and characterized by single X-ray diffraction and magnetic measurements. None of these salts shows a clear spin crossover behaviour and their magnetic properties are due essentially to the cations in a high spin S = 5/2 and low spin states for the FeIII and FeII salts respectively. The magnetic Ni sublattices in both compounds appear to have a negligible direct contribution to the magnetization but enhance the AF interactions in the cation sublattice.
Salts [Fe(sal2-trien)] [M(dcbdt)2] and [Fe(phen)3] [M(dcbdt)2]2with M = Ni and Au were obtained and characterized. Their magnetic properties are essentially due to the cations in a high spin S = 5/2 and low spin states for the FeIII and FeII salts respectively with no spin crossover.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 360, Issue 13, 1 October 2007, Pages 3887–3895