کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310462 | 975248 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of some oxovanadium(V) complexes with internally functionalized oximes: Crystal and molecular structures of heptacoordinated [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3] · 0.5C6H6
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and characterization of some oxovanadium(V) complexes with internally functionalized oximes: Crystal and molecular structures of heptacoordinated [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3] · 0.5C6H6 Synthesis and characterization of some oxovanadium(V) complexes with internally functionalized oximes: Crystal and molecular structures of heptacoordinated [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3] · 0.5C6H6](/preview/png/1310462.png)
چکیده انگلیسی
New oxovanadium(V) complexes with internally functionalized oximes, [VO{OPri}3ân{ONC(CH3)(Ar)}n] (where Ar = C4H3O-2, C4H3S-2 and C5H4N-2 and n = 1-3), have been prepared and characterized by spectroscopic techniques. The single crystal X-ray diffraction studies of [VO{ONC(CH3)(C4H3O-2)}3] and [VO{ONC(CH3)(C4H3S-2)}3] · 0.5C6H6 exhibit the presence of vanadium(V) atoms in a unique hepta-coordination state with the oximato ligands bonded in a dihapto (η2-N,O) manner.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 360, Issue 6, 20 April 2007, Pages 2009-2015
Journal: Inorganica Chimica Acta - Volume 360, Issue 6, 20 April 2007, Pages 2009-2015
نویسندگان
Vineet Sharma, Vinita Sharma, Rakesh Bohra, John E. Drake, Michael B. Hursthouse, Mark E. Light,