کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1310732 | 975258 | 2007 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pd(II) complexes containing N-alkyl-3-pyridine-5-trifluoromethyl pyrazole ligands: Synthesis, NMR studies and X-ray crystal structures
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Pd(II) complexes containing N-alkyl-3-pyridine-5-trifluoromethyl pyrazole ligands: Synthesis, NMR studies and X-ray crystal structures Pd(II) complexes containing N-alkyl-3-pyridine-5-trifluoromethyl pyrazole ligands: Synthesis, NMR studies and X-ray crystal structures](/preview/png/1310732.png)
چکیده انگلیسی
[PdCl2(L)] complexes with N-alkylaminopyrazole derived ligands, were synthesised. The crystal and molecular structures of [PdCl2(L)] (LÂ =Â L2, L3, L4) were resolved by X-ray diffraction, and it consists in monomeric cis-[PdCl2(L)] molecules. Reactoin of L (L2, L4) with [Pd(CH3CN)4](BF4)2 gave complexes [Pd(L)2](BF4)2. Treatment of [PdCl2(L)] (LÂ =Â L2, L4) with NaBF4 and pyridine (py) and with AgBF4 and triphenylphosphine (PPh3) yielded [Pd(L)(py)2)](BF4)2 and [Pd(L)(PPh3)2)](BF4)2 complexes, respectively. Finally, reaction of [PdCl2(L4)] with one equivalent of AgBF4 yields [PdCl(L4)](BF4).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 360, Issue 2, 1 February 2007, Pages 625-637
Journal: Inorganica Chimica Acta - Volume 360, Issue 2, 1 February 2007, Pages 625-637
نویسندگان
Vanessa Montoya, Josefina Pons, Jordi Garcia-Antón, Xavier Solans, Mercè Font-Bardia, Josep Ros,