کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1310965 | 975268 | 2006 | 6 صفحه PDF | دانلود رایگان |
The reaction of cyanamide and its derivatives with the (η5-C5H5)Mn(CO)2(THF) and (η5-C5H4CH3)Mn(CO)2(THF) complexes affords the cyanamide substituted complexes of types (η5-C5H5)Mn(CO)2(NCN(R′)(R″)) (2a–d) and (η5-C5H4CH3)Mn(CO)2(NCN(R′)(R″)) (3a–e). All complexes were characterized by spectroscopy (1H, 13C NMR, IR), elemental and mass spectroscopy analysis. Complex 2b (η5-C5H5)Mn(CO)2(NCN(CH3)2) was additionally examined by single crystal X-ray structure determination.
The reaction of cyanamide and its derivatives with (η5-C5H5)Mn(CO)2(THF) and (η5-C5H4CH3)Mn(CO)2(THF) complexes affords the cyanamide substituted complexes of types (η5-C5H5) Mn(CO)2(NCN(R′)(R″)) and (η5-C5H4CH3) Mn(CO)2(NCN(R′)(R″)).Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 359, Issue 15, 1 December 2006, Pages 4885–4890