کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311000 | 975273 | 2005 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Towards absolute asymmetric synthesis. Synthesis and crystal structure of stereochemically labile MCl2 (M = Co, Ni, Cu, Zn) complexes with diamine ligands Towards absolute asymmetric synthesis. Synthesis and crystal structure of stereochemically labile MCl2 (M = Co, Ni, Cu, Zn) complexes with diamine ligands](/preview/png/1311000.png)
In search for new conglomerates, seven stereochemically labile complexes between MCl2 (M = Co, Cu, Ni, Zn) and bidentate ligands, the commercially available N,N,N′-trimethylethane-1,2-diamine (trimeda) and the somewhat bulkier N-isopropyl-N,N′,N′-trimethylethane-1,2-diamine (itmeda), have been synthesized and characterized using single crystal X-ray diffraction. The trimeda and itmeda ligands exhibit chirogenic nitrogen centers and may form chiral metal complexes that are candidates for total spontaneous resolution. Copper(II) chloride forms the dimeric meso complexes [{CuCl2(trimeda)}2] (1) and [{CuCl2(itmeda)}2] (2), while [CoCl2(trimeda)2] (3) and [NiCl2(trimeda)2] (4) exhibit six-coordinate but chiral (R,R)- and (S,S)-complexes. Three examples of the chiral target complex, comprising four-coordinate stereochemically labile monomers, was successfully prepared, viz. [NiCl2(itmeda)] (5), [ZnCl2(itmeda)] (6), and [CoCl2(itmeda)] (7).In all seven complexes, the λ-conformation of the five-membered trimeda-metal chelate ring corresponds to the (S)-configuration at nitrogen, and vice versa. Supramolecular interactions in 3 and 4 form hydrogen-bonded heterochiral ribbons. However, crystals of 5–7 display homochiral interactions resulting in polar phases. Weak CH–Cl interactions in 5 and 6 form homochiral layers. In 7, interactions form homochiral helices along the a-axis.
Seven stereochemically labile complexes between MCl2 (M = Co, Cu, Ni, Zn) and N,N,N′-trimethylethane-1,2-diamine (trimeda) or N-isopropyl-N,N′,N′-trimethylethane-1,2-diamine (itmeda) have been synthesized and characterized by X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 358, Issue 12, 1 August 2005, Pages 3293–3302