کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1311028 975273 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
چکیده انگلیسی

Interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)13, and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)12X and Fe5O(OEt)11X2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)13 isolated with higher yields.

Interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)13, and its halide alkoxide analogs.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 358, Issue 12, 1 August 2005, Pages 3506–3512
نویسندگان
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