کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311028 | 975273 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide](/preview/png/1311028.png)
چکیده انگلیسی
Interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)13, and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)12X and Fe5O(OEt)11X2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)13 isolated with higher yields.
Interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)13, and its halide alkoxide analogs.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 358, Issue 12, 1 August 2005, Pages 3506–3512
Journal: Inorganica Chimica Acta - Volume 358, Issue 12, 1 August 2005, Pages 3506–3512
نویسندگان
Gulaim A. Seisenbaeva, Suresh Gohil, Evgeniya V. Suslova, Tatiana V. Rogova, Nataliya Ya. Turova, Vadim G. Kessler,