کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311301 | 975310 | 2010 | 9 صفحه PDF | دانلود رایگان |

Hydrothermal synthesis has afforded divalent cadmium coordination polymers containing bis(pyridylmethyl)piperazine (bpmp) tethers and either phenylenediacetate (phda) or phenylenedipropionate (phdp) ligands. {[Cd(1,4-phda)(4-bpmp)]·1.5H2O}n (1) displays a (4,4)-grid layered structure based on 4-connected {Cd2O2} dimeric units. Extension of the pendant arms generated {[Cd(1,4-phdp)(H4-bpmp)](ClO4)·3.5H2O}n (2, phdp = phenylenedipropionate), which possesses a rare (3,6) 2D trigonal lattice based on 6-connected {Cd2O2} dimers. Changing the nitrogen donor atom disposition by using 3-bpmp as the nitrogen co-ligand yielded [Cd(1,4-phdp)(3-bpmp)(H2O)]n (3), which crystallizes in a 3-fold interpenetrated achiral diamondoid lattice. [Cd(1,3-phda)(4-bpmp)]n (4) adopts a very similar structure to that of 1. Complexes 1–4 undergo blue-violet luminescence upon exposure to ultraviolet radiation.
Hydrothermal synthesis has afforded divalent cadmium coordination polymers containing bis(pyridylmethyl)piperazine (bpmp) tethers and either phenylenediacetate (phda) or phenylenedipropionate (phdp) ligands. {[Cd(1,4-phdp)(H4-bpmp)] (ClO4)·3.5H2O}n possesses a rare (3,6) 2D trigonal lattice. [Cd(1,4-phdp)(3-bpmp)(H2O)]n, crystallizes in a 3-fold interpenetrated achiral diamondoid lattice. The phda derivatives manifest dimer-based (4,4) rhomboid grids.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 1, 4 January 2010, Pages 88–96