کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1311427 975319 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of Fe(III)(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of Fe(III)(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2)
چکیده انگلیسی

Compounds FeIII(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2) (1, 1 · 2H2O) were synthesized and characterized: the structure of 1 and the magnetic properties of both compounds were determined. Compound 1 · 2H2O presents properties characteristic of high-spin Fe(III), while 1 presents properties of low-spin Fe(III) with an onset of a gradual spin crossover at ca. 300 K.

Compounds FeIII(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2) were synthesized and characterized. The hydrated one present properties characteristic of high-spin Fe(III), while the dry one of low-spin Fe(III). The dry compound has a beginning of spin crossover at high temperatures.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 6, 20 April 2009, Pages 2076–2079
نویسندگان
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