کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1311627 975339 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and structural characterization of adducts of silver (I) diethyldithiocarbamate with P-donor ligands
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and structural characterization of adducts of silver (I) diethyldithiocarbamate with P-donor ligands
چکیده انگلیسی

Adducts of triorganophosphines PR3, and diphosphines R2P(CH2)nPR2 with silver(I) diethyldithiocarbamate Ag(dtc) have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single-crystal X-ray structure analysis). The topology of the structures in the solid state was found to depend on the nature of the P-donor and on the Ag(dtc):P-donor stoichiometric ratio. In the mononuclear [(Ph2MeP)2Ag(dtc)] and [{(:CHPPh2)2}Ag(dtc)], four-coordinate P2AgS2 environments are found, as also in [(dtc)Ag(P′-dppm-P′)2Ag(dtc)] where the two Ag(dtc) moieties are linked by the pair of bidentate, bridging, dppm ligands; by contrast the dppp adduct Ag(dtc):dppp (1:1) is an infinite one-dimensional polymer. In the other complexes [(R3P)Ag(dtc)]2 structurally defined, the silver environment is PAgS3, two of the sulfur atoms drawn from the same dtc, now an unsymmetrical chelate, and one of the sulfur atoms bridged to the second silver atom.

Adducts of triorganophosphine PR3, and diphosphines R2P(CH2)nPR2 with silver(I) diethyldithiocarbamate Ag(dtc) have been prepared and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single-crystal X-ray structure analysis), the topology of the structures being dependent on the nature of the P-donor and on the Ag(dtc):P-donor stoichiometric ratio.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 360, Issue 9, 10 June 2007, Pages 2935–2943
نویسندگان
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