کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311817 | 975360 | 2005 | 13 صفحه PDF | دانلود رایگان |

A series of new thiophene amides containing a pyridine ring has been synthesized and characterized. Single crystal X-ray structures have been determined for four of the new substances which show two distinct patterns of hydrogen-bonding. The crystal structure of the copper (II) complex of one of the ligands shows that the bonding is O,N in a square planar geometry with perchlorate ions in the axial positions. The new compounds do not undergo electropolymerization due to primary oxidation of the amide function but tuning of the amide group by introduction of an electron-withdrawing group on the pyridine ring allows electropolymerization to occur.
A series of new thiophene amides containing a pyridine ring has been synthesized. Most of these compounds show the pattern of hydrogen-bonding indicated in the example above, but some exhibit a dimeric structure. These species can function as bidentate N,O ligands. Although these compounds do not undergo oxidative polymerization owing to primary oxidation of the amide group, polymerization can be effected by tuning of the pyridine ring.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 358, Issue 13, 1 September 2005, Pages 3711–3723