کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1311817 975360 2005 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of 3-thiophene carboxamides containing a pyridine ring: structure, electrochemistry, and complexation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of 3-thiophene carboxamides containing a pyridine ring: structure, electrochemistry, and complexation
چکیده انگلیسی

A series of new thiophene amides containing a pyridine ring has been synthesized and characterized. Single crystal X-ray structures have been determined for four of the new substances which show two distinct patterns of hydrogen-bonding. The crystal structure of the copper (II) complex of one of the ligands shows that the bonding is O,N in a square planar geometry with perchlorate ions in the axial positions. The new compounds do not undergo electropolymerization due to primary oxidation of the amide function but tuning of the amide group by introduction of an electron-withdrawing group on the pyridine ring allows electropolymerization to occur.

A series of new thiophene amides containing a pyridine ring has been synthesized. Most of these compounds show the pattern of hydrogen-bonding indicated in the example above, but some exhibit a dimeric structure. These species can function as bidentate N,O ligands. Although these compounds do not undergo oxidative polymerization owing to primary oxidation of the amide group, polymerization can be effected by tuning of the pyridine ring.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 358, Issue 13, 1 September 2005, Pages 3711–3723
نویسندگان
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