کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1311947 1499138 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
ONO pincer type binuclear Pd(II) complex: Synthesis, crystal structure and catalytic utilization of the resulting organopalladium complex in catalytic copper-free Sonogashira coupling reaction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
ONO pincer type binuclear Pd(II) complex: Synthesis, crystal structure and catalytic utilization of the resulting organopalladium complex in catalytic copper-free Sonogashira coupling reaction
چکیده انگلیسی


• A new binuclear palladium (II)-ONO pincer type complex.
• The catalytic activity towards the copper-free Sonogashira cross coupling reaction.
• Good reusability and low catalyst loading for the catalytic system.

New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed excellent catalytic activity towards the copper-free Sonogashira cross coupling reaction. The main advantages over previous methodologies include low catalyst loading, less problematic reaction media (H2O–DMSO) and reusability in homogenous systems for optimal performance.

New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed strong performance in copper-free Sonogashira coupling reaction between aryl halides and phenyl acetylene.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 451, 1 September 2016, Pages 227–232
نویسندگان
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