کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1311947 | 1499138 | 2016 | 6 صفحه PDF | دانلود رایگان |

• A new binuclear palladium (II)-ONO pincer type complex.
• The catalytic activity towards the copper-free Sonogashira cross coupling reaction.
• Good reusability and low catalyst loading for the catalytic system.
New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed excellent catalytic activity towards the copper-free Sonogashira cross coupling reaction. The main advantages over previous methodologies include low catalyst loading, less problematic reaction media (H2O–DMSO) and reusability in homogenous systems for optimal performance.
New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed strong performance in copper-free Sonogashira coupling reaction between aryl halides and phenyl acetylene.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 451, 1 September 2016, Pages 227–232