کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1312110 | 1499162 | 2015 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Hydrothermal synthesis and characterization of one dimensional chain structures of monolacunary Keggin polyoxoanions substituted with copper Hydrothermal synthesis and characterization of one dimensional chain structures of monolacunary Keggin polyoxoanions substituted with copper](/preview/png/1312110.png)
• [(4,4′bpyH2)2(4,4′bpyH)][PCuW11O39]·H2O and [4,4′bpyH2][pyH]3[PCuW11O39]·H2O were synthesized using hydrothermal method.
• The effect of pH of reaction media and stirring time are studied.
• Crystals were analysed using IR, TGA, magnetic measurements and X-ray diffraction.
• Molecules extends in 3D through hydrogen bonding.
Two novel polymeric polyoxometallates constructed from transition metal substituted heteropolytungstates, [(4,4′bpyH2)2(4,4′bpyH)][PCuW11O39]·H2O (1), and [(4,4′bpyH2)(pyH)3][PCuW11O39]·2H2O (2), (4,4′bpy = 4,4′bipyridine, py = pyridine) have been synthesized under hydrothermal conditions and characterized by IR, TGA, single crystal X-ray diffraction and magnetic measurements. The product formation showed a high sensitivity toward experimental factors including pH and stirring. Compounds 1 crystallizes in the monoclinic space group P2(1)/n with a = 13.503(3) Å, b = 26.726(5) Å, c = 15.168(3) Å, β = 99.61(3)° and Z = 4. The second compound also crystallizes in space group P2(1)/n, but with a = 13.519(3) Å, b = 20.431(4) Å, c = 18.655(4) Å, β = 96.52(3)° and Z = 4. Compound 1 exhibits a zigzag chain structure, while compound 2 exhibits a straight chain structure. Compound 2 is the first example of a polyoxometallate containing 1D chains of transition-metal-substituted heteropolytungstate designed with two significantly different organic units as the countercations. The Cu2+ ions in 1 exhibit paramagnetic behavior.
Two novel hybrid POMs based on the monolacunary Keggin anion [PCuW11O39]5− have been synthesized using hydrothermal methods and characterized using X-ray diffraction, IR, TGA and magnetic methods. Keggin units propagate as 1D chains in either a straight or a zigzag fashion.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 427, 1 March 2015, Pages 219–225