Synthesis and characterization of four coordination polymers constructed with d10 metals and mixed flexible ligands under solvothermal conditions

► Four coordination polymers have been solvothermally synthesized. ► Structural characterization reveals 2D and 3D polymeric networks. ► The solvents have important influence on the final topological structures. ► The observed luminescence in solid state is a consequence of intraligand π-π∗ transition.