کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1312457 1499197 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles
چکیده انگلیسی

New 18-membered cyclotriphosphazene-containing macrocycles 7-10 were obtained by 1 + 1 condensation reaction of [dispiro-N3P3(C12H8O2)2((N(Me)NCH)2 N4C20H26)] (2) with N,N′-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4-methyl-2-formylphenol) (3), N,N′-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4,5-dimethyl-2-formylphenol) (4), N,N′-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-chloro-2-formylphenol) (5) and N,N′-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-bromo-2-formylphenol) (6), respectively.

A facile procedure for the assembly of macrocycles containing cyclophosphazene rings. The phenol oxygen and imino and amino nitrogen atoms present in the macrocyclic cavity can be utilized for coordination to metal ions.Figure optionsDownload as PowerPoint slideHighlights
► We have designed and synthesized new macrocycles by condensation reaction.
► The condensation reaction is very selective and yield only 1 + 1 condensed product.
► The macrocycles can accommodate any metal ions.
► The macrocyclic cavity can be easily fin-tuned.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 390, 15 July 2012, Pages 163–166
نویسندگان
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