کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312463 | 1499204 | 2012 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Syntheses and properties of a series of oxo-centered triruthenium complexes with thiocyanate and nitrite as terminal ligand
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
⺠Linkage isomerism between N-bound nitrate and O-bound nitrate on the oxo-acetato triruthenium is affected by ancillary ligand. ⺠The [Ru3O(CH3CO2)6(NO2)(dmap)2] is obtained as a single isomer having N-bound nitrate, whereas the [Ru3O(CH3CO2)6(NO2)(py)2] is obtained as a mixture of linkage isomers, having N-bound nitrate and O-bound nitrate. ⺠X-ray crystallography of [Ru3O(CH3CO2)6(NCS)(C5H5N)2]·2CH2Cl2 reveals that the NCS coordinates linearly, and the triangle formed by the three rutheniums is almost equilateral. ⺠The first example of oxo-carboxylato triruthenium complex with negative charge.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 383, 30 March 2012, Pages 1-6
Journal: Inorganica Chimica Acta - Volume 383, 30 March 2012, Pages 1-6
نویسندگان
Hiroyoshi Ohtsu, Naoki Oka, Tadashi Yamaguchi,