کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1312564 975467 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A metallopolymer, [Cu(abt)]∞ (abt, 2-aminobenzenethiol) with novel structural patterns resembling black phosphorus
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A metallopolymer, [Cu(abt)]∞ (abt, 2-aminobenzenethiol) with novel structural patterns resembling black phosphorus
چکیده انگلیسی

A copper(I) complex of 2-aminobenzenethiol, [Cu(abt)]∞ (1), has been synthesized and characterized. The crystal structure determination indicates a two-dimensional metallopolymeric network formed by edge and corner sharing [Cu(μ3-S)N] coordination tetrahedra wherein the copper(I) centers are coordinated to three bridging thiolate donors and the amino group of 2-aminobenzenethiolate. The copper, the sulfur and the nitrogen atoms form sub-lattices that reveal independently striking similarities to the double-layers present in black phosphorus.

The polymeric complex, [Cu(abt)]∞ shows unique tetrahedral connectivity and – reduced to the copper–sulfur arrangement – close structural resemblance to the double-layer lattice of black phosphorus.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 363, Issue 10, 20 June 2010, Pages 2144–2148
نویسندگان
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