کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312588 | 975467 | 2010 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Novel palladium(II) and platinum(II) complexes of biocidal benzisothiazolinone (Bit); X-ray crystal structures of co-crystallised Bit/BitO and cis-Pd(en)(Bit−1H)2·H2O Novel palladium(II) and platinum(II) complexes of biocidal benzisothiazolinone (Bit); X-ray crystal structures of co-crystallised Bit/BitO and cis-Pd(en)(Bit−1H)2·H2O](/preview/png/1312588.png)
Reaction of benzisothiazolinone (Bit), a well-known biocide, with the Pd(II) and Pt(II) am(m)ine precursors cis-[Pd(en)(H2O)2](NO3)2 and cis-[Pt(NH3)2(H2O)2](NO3)2 yielded cis-Pd(en)(Bit−1H)2 and cis-Pt(NH3)2(Bit−1H)2, respectively. Bit is bound to the metal centres in both cases through the deprotonated isothiazolinone N. The crystal structures of a Bit/BitO co-crystal and cis-Pd(en)(Bit−1H)2·H2O are also described.
Two novel Pd(II) and Pt(II) complexes of the potent biocide benzisothiazolinone (Bit), cis-Pd(en)(Bit−1H)2 and cis-[Pt(NH3)2(Bit−1H)2], have been synthesised and characterised. Bit is bound to the metal centres in both cases through the deprotonated isothiazolinone N. The crystal structures of a Bit/BitO co-crystal and cis-Pd(en)(Bit−1H)2·H2O are also described.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 10, 20 June 2010, Pages 2333–2337