کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1312590 | 975467 | 2010 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and structural characterization of two donor-functionalized terphenyl magnesium compounds Synthesis and structural characterization of two donor-functionalized terphenyl magnesium compounds](/preview/png/1312590.png)
The synthesis and structural characterization of two novel donor-functionalized terphenyl magnesium compounds, namely (Danip)2Mg (1) [Danip = 2,6-di(o-anisyl)phenyl] and [DinapOMg(THF)]2 (Dinap = 2,6-di(o-2-methoxynaphthyl)phenyl; DinapO = 2-(o-2-methoxynaphthyl)-6-(o-2-naphthoxide)phenyl) is reported. Compound 1 represents a first structurally authenticated bis terphenyl magnesium compound, while the molecular structure of dimeric tetrahydrofuran solvated 2 shows a five-coordinate magnesium atom stabilized by a partially demethylated dianionic mixed arylether/aryloxide terphenyl ligand (= DinapO).
The synthesis and X-ray crystal structure determination of two terphenyl based magnesium compounds is reported. The compound shown represents a first example of a bis terphenyl compound of the element magnesium.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 363, Issue 10, 20 June 2010, Pages 2341–2344