کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312680 | 975482 | 2009 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Catalytic oxidation of alkenes by manganese(III) porphyrin-encapsulated Al, V, Si-mesoporous molecular sieves Catalytic oxidation of alkenes by manganese(III) porphyrin-encapsulated Al, V, Si-mesoporous molecular sieves](/preview/png/1312680.png)
Cationic manganese-porphyrin, [meso-tetrakis(4-trimethylammoniophenyl)porphyrinato]manganese(III) pentachloride (MnTAPP), has been prepared and encapsulated into mesoporous molecular sieves Al-MCM-41 and V-MCM-41, containing different amounts of Al and V, respectively. The catalytic activities of these heterogeneous materials were tested in the liquid phase oxidation of cyclohexene and styrene in acetonitrile with iodosylbenzene (PhIO) as oxygen source. Both types of catalysts were active in the oxidation reaction. MnTAPP encapsulated in Al-MCM-41 produces allylic oxidation products alone and no epoxide with styrene was found. However, it produces both epoxide and allylic oxidation products with cyclohexene. At the same time, MnTAPP encapsulated in V-MCM-41 produces epoxide as major product and little allylic oxidation product with styrene, while both epoxide and allylic oxidation products were obtained with cyclohexene. It is suggested that the regioselective effect is due to relatively more acidic Al-MCM-41 than V-MCM-41 which could make the CC bond unreactive towards epoxidation and produces allylic oxidation product. With increasing Al or V content in the support, the porphyrin loading was found to increase, which in turn increases the catalytic activity of the heterogeneous systems. The heterogeneous catalysts were reused for three times. The selectivity of these heterogeneous catalysts does not change appreciably even after three times of reusing, but their catalytic activity decreases marginally. This may be attributed to catalyst leaching and/or decomposition of MnTAPP complex under the reaction conditions.
The cationic manganese-porphyrin, [meso-tetrakis(4-trimethylammoniophenyl)porphyrinato]manganese(III) pentachloride(MnTAPP) was encapsulated on well-defined pores of Al/V substituted mesoporous materials. The catalytic activity of the synthesized composites are controlled by Si/M ratio, where M is Al or V. These heterogeneous catalysts were reused successively under the same experimental conditions.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 362, Issue 5, 1 April 2009, Pages 1491–1500