کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312706 | 975482 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and crystal structure of one-dimensional zinc(II) polymer constructed by salicylate and trans-1,2-bis(4-pyridyl)ethylene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new zinc(II) compound, [Zn2(Hsal)4(4,4â²-bpe)2] · [Zn(Hsal)2(4,4â²-bpe)(DMF)(H2O)] · CH3OH (1) (Hsal = salicylate and 4,4â²-bpe = trans-1,2-bis(4-pyridyl)ethylene) has been synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The crystal structure consists of three independent moieties: [Zn2(Hsal)4(4,4â²-bpe)2], [Zn(Hsal)2(4,4â²-bpe)(DMF)(H2O)], and non-coordinated CH3OH molecule. In the compound two independent moieties which are connected by 4,4â²-bpe to form 1-D chains, respectively, are further expended to accomplish 2-D network through hydrogen-bonding interactions between non-coordinated methanol and coordinated water molecule or carboxylate oxygen atoms of Hsal ligands.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 362, Issue 5, 1 April 2009, Pages 1655-1659
Journal: Inorganica Chimica Acta - Volume 362, Issue 5, 1 April 2009, Pages 1655-1659
نویسندگان
Eun Ju Jung, Uk Lee, Bon Kweon Koo,