کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312843 | 975502 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dimerization and polymeric self-arrangement of [HgII(Py)2(PhN2C6H4NNNC6H4R)2] (Py = pyridine; R = NO2) through reciprocal metal-η2-arene Ï-interactions and non-classical C-Hâ¯O bonding: Synthesis and X-ray characterization of a polyaryl asymmetric-
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dimerization and polymeric self-arrangement of [HgII(Py)2(PhN2C6H4NNNC6H4R)2] (Py = pyridine; R = NO2) through reciprocal metal-η2-arene Ï-interactions and non-classical C-Hâ¯O bonding: Synthesis and X-ray characterization of a polyaryl asymmetric- Dimerization and polymeric self-arrangement of [HgII(Py)2(PhN2C6H4NNNC6H4R)2] (Py = pyridine; R = NO2) through reciprocal metal-η2-arene Ï-interactions and non-classical C-Hâ¯O bonding: Synthesis and X-ray characterization of a polyaryl asymmetric-](/preview/png/1312843.png)
چکیده انگلیسی
3-(4-Phenyldiazophenyl)-1-(4-nitrophenyl)triazenide reacts with Hg(CH3COO)2 and pyridine to give {[HgII(Py)2(PhN2C6H4NNNC6H4R)2]2}n (Py = pyridine; R = NO2), the first reported HgII-Py complex with two coordinating pyridine molecules. The tectons [HgII(Py)2(PhN2C6H4NNNC6H4R)2] are linked to pairs as centrosymmetric dimers through reciprocal metal-η2-arene Ï-interactions. The dimers are assembled by translation on the ac plane to unidimensional chains linked through non classical C-Hâ¯O hydrogen bonds.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 14, 1 November 2006, Pages 4667-4671
Journal: Inorganica Chimica Acta - Volume 359, Issue 14, 1 November 2006, Pages 4667-4671
نویسندگان
Manfredo Hörner, Gelson Manzoni de Oliveira, Lorenzo do Canto Visentin, Renato Silveira Cezar,