کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1312852 975507 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and structural characterization of several dirhenium(III) compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and structural characterization of several dirhenium(III) compounds
چکیده انگلیسی

Reaction between Re2(OAc)4Cl2 and N,N′-dicyclohexylbenzamidine (HDCyBA) under molten conditions yielded Re2(DCyBA)2Cl4 (1); reaction of [Bu4N]2[Re2Cl8] with N,N′-di(3-methoxyphenyl)formamidine (HDmAniF) resulted in Re2(DmAniF)2Cl4 (2); reaction of cis-Re2(OAc)2Cl4 with HDmAniF under reflux conditions resulted in cis-Re2(OAc)2(DmAniF)2Cl2 (3). Reaction between Re2(OAc)4Cl2 and α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid (H2esp) under reflux conditions led to Re2(esp)2Cl2 (4). Crystallographic studies of compounds 1–4 revealed Re–Re bond lengths of 2.1679(6), 2.1804(5), 2.2468(7), and 2.2304(6) Å, respectively, which are consistent with the presence of Re–Re quadruple bond. Also reported are electrochemical properties of compounds 1–4.

Novel dirhenium compounds containing labile groups have been prepared and characterized.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 13, 1 October 2006, Pages 4191–4196
نویسندگان
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