کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312921 | 975512 | 2006 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2]. The crystal structures of trans-[Pd(PPh3)2(SC6H4-2-SiPh3)2], z-[Pt(PPh3)2(Cl)(SC6H4-2-SiPh3)], e-[Pt(PPh3)2(Cl)(SC6H4-2-SiCH3Ph2)], cis-
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2]. The crystal structures of trans-[Pd(PPh3)2(SC6H4-2-SiPh3)2], z-[Pt(PPh3)2(Cl)(SC6H4-2-SiPh3)], e-[Pt(PPh3)2(Cl)(SC6H4-2-SiCH3Ph2)], cis- Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2]. The crystal structures of trans-[Pd(PPh3)2(SC6H4-2-SiPh3)2], z-[Pt(PPh3)2(Cl)(SC6H4-2-SiPh3)], e-[Pt(PPh3)2(Cl)(SC6H4-2-SiCH3Ph2)], cis-](/preview/png/1312921.png)
چکیده انگلیسی
The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] was examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. The formulation of these complexes was dependent of the stoichiometry and relative size of the metal and the thiolate. Analogous reactions with nickel complexes afforded disulfides products of the oxidation of the thiols.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 12, 1 September 2006, Pages 4007-4018
Journal: Inorganica Chimica Acta - Volume 359, Issue 12, 1 September 2006, Pages 4007-4018
نویسندگان
Viviana Cordero-Pensado, Valente Gómez-BenÃtez, Simón Hernández-Ortega, Rubén A. Toscano, David Morales-Morales,