کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1313158 975532 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Coordination chemistry of acrylamide 3: Synthesis, crystal structure and IR spectroscopic properties of dichloro-tetrakis(O–acrylamide)copper(II), [Cu(O–OC(NH2)CHCH2)4Cl2]
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Coordination chemistry of acrylamide 3: Synthesis, crystal structure and IR spectroscopic properties of dichloro-tetrakis(O–acrylamide)copper(II), [Cu(O–OC(NH2)CHCH2)4Cl2]
چکیده انگلیسی

The molecular structure of copper(II) chloride complex with acrylamide (AAmCH2CHCONH2), [Cu(AAm)4Cl2], was determined using X-ray diffraction analysis. The complex crystallizes in the cubic space group I-43d with a = 17. 8310(2) Å, β = 90°, and V = 5669.27(11) Å3 for Z = 12. The acrylamide molecules bind to the metal center via the carbonyl oxygen atom (Cu–O 1.996 Å). The coordination geometry of the metal center in the complex involves a tetragonally distorted octahedral structure with four O-donor atoms of acrylamide bonded in the equatorial positions and two chlorides in the apical positions. Comparison of crystal structure data of acrylamide and metal acrylamide complexes of those formed with divalent transition metal chlorides has been summarized.

The molecular structure of copper(II) chloride complex with acrylamide (AAmCH2CHCONH2), [Cu(AAm)4Cl2], was determined using X-ray diffraction analysis. The acrylamide molecules bind to the metal center via the carbonyl oxygen atom (Cu–O 1.996 Å). The coordination geometry of the metal center in the complex involves a tetragonally distorted octahedral structure with four O-donor atoms of acrylamide bonded in the equatorial positions and two chlorides in the apical positions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 359, Issue 1, 1 January 2006, Pages 364–368
نویسندگان
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