کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1313180 | 975537 | 2005 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Structural change of supramolecular coordination polymers of itaconic acid and 1,10-phenanthroline along lanthanide series Structural change of supramolecular coordination polymers of itaconic acid and 1,10-phenanthroline along lanthanide series](/preview/png/1313180.png)
Five new supramolecular lanthanide coordination polymers with three different structures, {[La2(IA)3(phen)2] · 2H2O}n (1), {[Ln(IA)1.5(phen)] · xH2O}n [x = 1, Ln = Eu (2); x = 0.25, Ln = Dy (3)], and [Ln(IA)1.5(phen)]n [Ln = Er (4); Yb (5)], were prepared by hydro- and solvothermal reactions of lanthanide chlorides with itaconic acid (H2IA) and 1,10-phenanthroline (phen), and structurally characterized by single crystal X-ray diffraction. 1 Comprises 1-D double-chains that are further assembled to a 3-D supramolecular structure via hydrogen bonds and π–π stacks between phen molecules. 2 and 3 have 2-D infinite networks which are further constructed to form 3-D supramolecular architectures with 1-D channels by π–π aromatic interactions. 4 and 5 have 2-D layer structures consisting of three types of rings which are further architectured to form 3-D supramolecular structures by C–H⋯O hydrogen bonds. The H2IA ligands are all completely deprotonated and exhibit tetra-, penta-, and hexadentate coordination modes in the titled complexes. The high-resolution emission spectrum of 2 shows only one Eu3+ ion site in 2, which is in agreement with the result of X-ray diffraction. And the magnetic property and the thermal stability of 2 were also investigated.
Five new supramolecular lanthanide coordination polymers of itaconic acid and 1,10-phenanthroline, {[La2(IA)3(phen)2] · 2H2O}n (1), {[Ln(IA)1.5(phen)] · xH2O}n [x = 1, Ln = Eu (2); x = 0.25, Ln = Dy (3)], and [Ln(IA)1.5(phen)]n [Ln = Er (4); Yb (5)], with three different structures were obtained by hydro- and solvothermal techniques and structural changes along lanthanide series were discussed.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 358, Issue 9, 1 June 2005, Pages 2687–2696